Volcanoes Around The World

Large, explosive volcanic eruptions inject water vapor (H2O), carbon dioxide (CO2), sulfur dioxide (SO2), hydrogen chloride (HCl), hydrogen fluoride (HF) and ash (pulverized rock and pumice) into the stratosphere to heights of 16–32 kilometres (10–20 mi) above the Earth's surface. The most significant impacts from these injections come from the conversion of sulfur dioxide to sulfuric acid (H2SO4), which condenses rapidly in the stratosphere to form fine sulfate aerosols. The aerosols increase the Earth's albedo—its reflection of radiation from the Sun back into space – and thus cool the Earth's lower atmosphere or troposphere; however, they also absorb heat radiated up from the Earth, thereby warming the stratosphere. Several eruptions during the past century have caused a decline in the average temperature at the Earth's surface of up to half a degree (Fahrenheit scale) for periods of one to three years — sulfur dioxide from the eruption of Huaynaputina probably caused the Russian famine of 1601 - 1603.
One proposed volcanic winter happened c. 70,000 years ago following the supereruption of Lake Toba on Sumatra island in Indonesia. According to the Toba catastrophe theory to which some anthropologists and archeologists subscribe, it had global consequences, killing most humans then alive and creating a population bottleneck that affected the genetic inheritance of all humans today. The 1815 eruption of Mount Tambora created global climate anomalies that became known as the "Year Without a Summer" because of the effect on North American and European weather. Agricultural crops failed and livestock died in much of the Northern Hemisphere, resulting in one of the worst famines of the 19th century. The freezing winter of 1740–41, which led to widespread famine in northern Europe, may also owe its origins to a volcanic eruption.
It has been suggested that volcanic activity caused or contributed to the End-Ordovician, Permian-Triassic, Late Devonian mass extinctions, and possibly others. The massive eruptive event which formed the Siberian Traps, one of the largest known volcanic events of the last 500 million years of Earth's geological history, continued for a million years and is considered to be the likely cause of the "Great Dying" about 250 million years ago, which is estimated to have killed 90% of species existing at the time.
The sulfate aerosols also promote complex chemical reactions on their surfaces that alter chlorine and nitrogen chemical species in the stratosphere. This effect, together with increased stratospheric chlorine levels from chlorofluorocarbon pollution, generates chlorine monoxide (ClO), which destroys ozone (O3). As the aerosols grow and coagulate, they settle down into the upper troposphere where they serve as nuclei for cirrus clouds and further modify the Earth's radiation balance. Most of the hydrogen chloride (HCl) and hydrogen fluoride (HF) are dissolved in water droplets in the eruption cloud and quickly fall to the ground as acid rain. The injected ash also falls rapidly from the stratosphere; most of it is removed within several days to a few weeks. Finally, explosive volcanic eruptions release the greenhouse gas carbon dioxide and thus provide a deep source of carbon for biogeochemical cycles.